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原著論文（査読付き）

H. Hori, K. Okamoto, K. SUzuki, M. Biermann,"Efficient mineralization of fluoroelastomers using superheated water in the presence of potassium hydroxide"ACS Omega, 2024, 9(20), 22398-22409. DOI:10.1021/acsomega.4c02097

J.Hamaura, H. Hori,A. Fujishima. H. Mukae, "Efficient mineralization of fluoroelastomers using superheated water in the presence of potassium hydroxide"Moleculess, 2023, 28(20), 7057. DOI:10.3390/molecules28207057

B. Ameduri, H. Hori, "Recycling and the end of life assessment of fluoropolymers: recent developments, challenges and future trends"Chemical Society Reviews, 2023, 52, 4208-4247. DOI:10.1039/d2cs00763k

J. Hamaura, R. Honma, H. Hori, A. Manseri, B. Ameduri, "Efficient fluoride recovery from poly(vinylidene fluoride), poly(vinylidene fluoride-co-hexafluoropropylene) copolymer and poly(ethylene-co-tetrafluoroethylene) copolymer using superheated water with alkaline reagent" European Polymer Journal, 2023, 182, 111724. DOI:10.1016/j.eurpolymj.2022.111724

堀　久男、亜臨界水を用いた次世代有機フッ素材料の分解・無機化反応の開発、環境技術, 2022, 51(5), 246-250.

H. Hori, Y. Yonezato, K. Ito,“Recovery of platinum and rhenium using selective precipitation induced by two-stage photochemical treatment" Hydrometallurgy, 2022, 211, 105883. DOI:10.1016/j.hydromet.2022.105883

H. Hori, R. Honma, K. Igarashi, A. Manseri, B. Ameduri,“Oxidative mineralization of poly[vinylidene fluoride-co-2- (trifluoromethyl)acrylic acid] copolymers in superheated water" Industrial & Engineering Chemistry Research, 2022, 61, 1386-139. DOI:10.1021/acs.iecr.1c04299

H. Hori, J. Hamaura,“Efficient mineralization of ethylene-tetrafluoroethylene copolymer in superheated water with permanganate" Polymer Degradation and Stability, 2021, 190, 109621. DOI:10.1016/j.polymdegradstab.2021.109621

堀　久男、高温高圧水を用いた有機フッ素化合物および有機ケイ素化合物の分解・無害化、再資源化反応の開発、 水環境学会誌, 2021, 44(A),7, 213-216.

H. Hori,“Decomposition of fluorinated ionic liquids to fluoride ions using superheated water: An efficientapproach for recovering fluorine from the waste of fluorinated ionic liquids" Electrochemistry, 2021, 89,75-82. DOI:10.5796/electrochemistry.20-65147

H. Hori, T. Ushio,T. Asai, R. Honma, N. Eid, B. Ameduri,“Efficient mineralization of a novel fluorotelomer surfactant, 2H,3H,3H,5H,5H,6H,6H-4-thia-perfluoro(2-methyl)-1-dodecanoic acid, in superheated water induced by a combination of potassium permanganate and dioxygen" Chemical Engineering Journal, 2021, 405, 127006. DOI:10.1016/j.cej.2020.127006

H. Hori, R. Honma,“Decomposition of fluoropolymers by their mineralization in subcritical water" Opportunities for Fluoropolymers: Synthesis, Characterization, Processing, Simulation and Recycling, Progress in Fluorine Science Series, 2020, 303-331. DOI:10.1016/B978-0-12-821966-9.00011-0

H. Hori, S. Oishi, H. Kato, R. Kodama,“Complete Mineralization of Fluorinated Ionic Liquids in Subcritical Water in the Presence of Potassium Permanganate" Industrial & Engineering Chemistry Research, 2020, 59, 5566-5575. DOI:10.1021/acs.iecr.9b06198

R. Honma, H. Hori, F. Reis da Cunha, N. Horiike, L. Steinbach, B. Ameduri,“Permanganate-induced efficient mineralization of poly(vinylidene fluoride) and vinylidene-fluoride based copolymers in low-temperature subcritical water" Industrial & Engineering Chemistry Research, 2019, 58, 13130-13040. DOI:10.1021/acs.iecr.9b01921

H. Hori, T. Kakizawa, N. Kuriyama, A. Kabuki, M. Otsuki, Y. Horii,“Decomposition of environmentally persistent cyclic methylsiloxanes in subcritical water" Sustainable Chemistry and Pharmacy, 2019, 13, 100160. DOI:10.1016/j.scp.2019.100160

H. Hori, T. Otsu, T. Yasukawa, R.Morita, S. Ishii, T. Asai,“Recovery of rhenium from aqueous mixed metal solutions by selective precipitation: A photochemical approach" Hydrometallurgy, 2019, 183, 151-158. DOI:10.1016/j.hydromet.2018.12.003

S. Banerjee, J. Schmid, Y. Talmon, H. Hori, T. Asai, B. Ameduri,“A degradable fluorinated surfactant for emulsion polymerization of vinylidene fluoride" Chemical Communications, 2018, 54, 11399-11402. DOI:10.1039/c8cc05290e

H. Hori, K. Ogi, Y. Fujita, Y. Yasuda, E. Nagashima, Y. Matsuki, K. Nomiya,“Oxidative removal of dibenzothiophene and related sulfur compounds from fuel oils under pressurized oxygen at room temperature with hydrogen peroxide and a phosphorus-free catalyst: sodium decatungstate" Fuel Processing Technology, 2018, 179, 175-183. DOI:10.1016/j.fuproc.2018.07.003

H. Hori, S. Wachi, K. Iwamura, S. Sano,“Visible light-induced decomposition of monoethanolamine in water using graphitic carbon nitride as a photocatalyst" Journal of Photochemistry and Photobiology A: Chemistry , 2018, 351,162-169. DOI:10.1016/j.jphotochem.2017.10.015

H. Hori, A. Kamijo, M. Inoue, A. Chino, Q. Wu, K. Kannan,“Efficient decomposition of perchlorate to chloride ions in subcritical water by use of steel slag" Environmental Science and Pollution Research, 2018, 25, 7262-7270. DOI:10.1007/s11356-016-7332-7

H. Hori, H. Tanaka, T. Tsuge, R. Honma, S. Banerjee, B. Ameduri,“Decomposition of fluoroelastomer: Poly(vinylidene fluoride-ter-hexafluoropropylene-ter-tetrafluoroethylene) terpolymer in subcritical water" European Polymer Journal, 2017, 94, 322-331. DOI:10.1016/j.eurpolymj.2017.05.042

堀　久男、亜臨界水を用いた機能性フッ素材料の分解・再資源化反応の開発、 スマートプロセス学会誌, 2017, 6(6),211-216. DOI:10.7791/jspmee.6.211


H. Hori, R. Manita, K. Yamamoto, S. Kutsuna, M. Kato,“Efficient photochemical decomposition of trifluoroacetic acid and its analogues with electrolyzed sulfuric acid" Journal of Photochemistry and Photobiology A: Chemistry, 2017, 332, 167-173. DOI:10.1016/j.jphotochem.2016.08.021

H. Hori, A. Takahashi, T. Ito,“Efficient FeO-induced decomposition of the fluorinated room-temperature ionic liquid [Me3PrN][(CF3SO2)2N] to fluoride ions in subcritical and supercritical water", Journal of Fluorine Chemistry, 2016, 186, 60-65. DOI:10.1016/j.jfluchem.2016.04.007

堀　久男、有機フッ素化合物の国際規制動向と分解無害化・再資源化反応の開発、オレオサイエンス, 2016, 16(3), 111-118. DOI:10.5650/oleoscience.16.111

H. Hori, Y. Yoshimura, T. Otsu, K. Kume, Y. Mitsumori, S. Kutsuna, K. Koike,“Efficient photochemical recovery of rhenium from aqueous solutions", Separation and Purification Technology, 2015, 156, 242-248. DOI:10.1016/j.seppur.2015.10.007

H. Hori, H. Tanaka, K. Watanabe, T. Tsuge, T. Sakamoto, A. Manseri, B. Ameduri, “Hydrogen peroxide induced efficient mineralization of poly(vinylidene fluoride) and related copolymers in subcritical water”, Industrial & Engineering Chemistry Research, 2015, 54(35), 8650-8658. DOI:10.1021/acs.iecr.5b01716

H. Hori, H. Yokota, “Efficient oxygen-induced decomposition of triphenylsulfonium trifluoromethanesulfonate to fluoride ions in subcritical water”, Journal of Fluorine Chemistry, 2015, 178, 1-5. DOI: 10.1016/j.jfluchem.2015.06.012

H. Hori, H. Saito, H. Sakai, T. Kitahara, T. Sakamoto, “Efficient decomposition of a new fluorochemical surfactant: Perfluoroalkane disulfonate to fluoride ions in subcritical and supercritical water”, Chemosphere, 2015, 129, 27-32. DOI: 10.1016/j.chemosphere.2014.06.052

H. Hori, T. Sakamoto, T. Tanabe, M. Kasuya, A. Chin, Q. Wu, K. Kannan, “Iron-induced efficient decomposition of perchlorate using pressurized hot water”, Organohalogen Compounds, 2014, 76, 454-458.

H. Hori, T. Sakamoto, K. Ohmura, H. Yoshikawa, T. Seita, T. Fujita, Y. Morizawa, “Efficient-oxygen induced mineralization of melt-processable fluoropolymers in subcritical and supercritical Water”, Industrial & Engineering Chemistry Research, 2014, 53 (17), 6934-6940. DOI: 10.1021/ie500446s

H. Hori, A. Ishiguro, K. Nakajima, T. Sano, S. Kutsuna , K. Koike, “Visible light-induced decomposition of a fluorotelomer unsaturated carboxylic acid in water with a combination of tungsten trioxide and persulfate”, Chemosphere, 2013, 93 (11), 2657-2922. DOI: 10.1016/j.chemosphere.2013.09.024

H. Hori, Y. Noda, A. Takahashi, T. Sakamoto, “Decomposition of perfluorinated ionic liquid anions to fluoride ions in subcritical and supercritical water with iron-based reducing agents”, Industrial & Engineering Chemistry Research, 2013, 52(38), 13622-13628. DOI: 10.1021/ie4017573

Y. Patil, H. Hori, H. Tanaka, T. Sakamoto, B. Ameduri, “First radical homopolymerisation of 2-trifluoromethacrylic acid in water and study of the degradation of the resulting homopolymers”, Chemical Communications, 2013, 49, 6662-6664. DOI: 10.1039/C3CC42395F

H. Hori, T. Sakamoto, T. Tanabe, M. Kasuya, A. Chino, Q. Wu, K. Kannan, “Metal-induced decomposition of perchlorate in pressurized hot water”, Chemosphere, 2012, 89, 737-742. DOI: 10.1016/j.chemosphere.2012.07.003

H. Hori, Y. Nagano, M. Murayama, K. Koike, S. Kutsuna, “Efficient decomposition of perfluoroether carboxylic acids in water with a combination of persulfate oxidant and ultrasonic irradiation”, J. Fluorine Chem., 2012, 141, 5-10. DOI: 10.1016/j.jfluchem.2012.05.012

H. Hori, T. Sakamoto, Y. Kimura, A. Takai, “Iron-induced efficient mineralization of a cyclic perfluoroalkyl surfactant in subcritical and supercritical water”, Catal. Today, 2012, 196 (1) 132-136. DOI: 10.1016/j.cattod.2012.02.032

S. Kutsuna, H. Hori, T. Sonoda, T. Iwakami, A. Wakisaka, “Preferential solvation of perfluorooctanoic acid (PFOA) by methanol in methanol water mixtures: A potential overestimation of the dissociation constant of PFOA using a Yasuda Shedlovsky plot”, Atmospheric Environment 2012, 49, 411-414. DOI: 10.1016/j.atmosenv.2011.12.009

堀　久男、村山美沙子、忽那周三、フッ素系イオン交換膜の亜臨界水分解、用水と廃水、2011, 53(11),70-77.

S. Kutsuna, H. Hori, M. Naganuma, A. Shimono, “Solubility and hydrolysis of HCFC-22(CHF2Cl): Upward revision of rate constants for aqueous reactions of CHF2Cl with OH- at elevated temperature”, Int. J. Chem. Kinet., 2011, 43, 639-647. DOI: 10.1002/kin.20596

H. Hori, K. Ishida, N. Inoue, K. Koike, S. Kutsuna, “Photocatalytic mineralization of hydroperfluorocarboxylic acids with heteropolyacid H4SiW12O40 in water”, Chemosphere, 2011, 82(8), 1129-1134. DOI: 10.1016/j.chemosphere.2010.11.038

H. Hori, M. Murayama, N. Inoue, K. Ishida, S. Kutsuna, “Efficient mineralization of hydroperfluorocarboxylic acids with persulfate in hot water”, Catal. Today, 2010, 151 (1-2), 131-136. DOI: 10.1016/j.cattod.2010.02.023

H. Hori, M. Murayama, T. Sano, S. Kutsuna, “Decomposition of perfluorinated ion-exchange
membrane to fluoride ions using zerovalent metals in subcritical water”, Ind. Eng. Chem. Res., 2010, 49 (2), 464-471. DOI: 10.1021/ie9004699

H. Hori, M. Murayama, S. Kutsuna, “Oxygen-induced efficient mineralization of perfluoroalkylether sulfonates in subcritical water, Chemosphere, 2009, 77, 1400-1405. DOI: 10.1016/j.chemosphere.2009.09.013

S. Kutsuna, K. Koike, H. Hori, "Rate constants and conversion ratios for aqueous-phase reactions of SO4- with CnF2n+1C(O)O- (n = 4-7) at 298 K", Int. J. Chem. Kinet., 2009, 41(12),735-747. DOI: 10.1002/kin.20239

堀　久男、村山美沙子、忽那周三、ペルオキソ二硫酸イオンを用いた環境残留性ペルフルオロカルボン酸類および代替フッ素化合物の温水分解、用水と廃水、2009, 51(9),71-77.

S. Kutsuna, H. Hori, “Experimental determination of Henry’s law constant of perfluorooctanoic acid (PFOA) at 298 K by means of an inert-gas stripping method with a helical plate”, Atmospheric Environment, 2008, 42, 8883-8892. DOI: 10.1016/j.atmosenv.2008.09.008

H. Hori, Y. Nagaoka, M. Murayama, S. Kutsuna, “Efficient decomposition of perfluorocarboxylic acids and alternative fluorochemical surfactants in hot water”, Environ. Sci. Technol., 2008, 42, 7438-7443. DOI: 10.1021/es800832p

H. Hori, A. Yamamoto, K. Koike, S. Kutsuna, M. Murayama, A. Yoshimoto, R. Arakawa, “Photocatalytic decomposition of a perfluoroether carboxylic acid by tungstic heteropolyacids in water”, Appl. Catal. B, Environ., 2008, 82 (1-2) 58-66. DOI: 10.1016/j.apcatb.2008.01.031

R. Shibata, K. Koike, H. Hori, H. Tamiaki, “Self-aggregation of synthetic zinc chlorophyll derivatives possessing fluoroalkyl chains in liquid carbon dioxide as models of green photosynthetic bacterial antennae”, Chem. Lett., 2008, 37, 532-533.

S. Kutsuna, H. Hori, “Experimantal determination of Henry’s law constants of trifluoroacetic acid at 278-298 K”, Atmos. Environ., 2008, 42, 1399-1412. DOI: 10.1016/j.atmosenv.2007.11.009

H. Hori, Y. Nagaoka, T. Sano, S. Kutsuna, “Iron-induced decomposition of perfluorohexanesulfonate in sub- and supercritical water”, Chemosphere, 2008, 70, 800-806. DOI: 10.1016/j.chemosphere.2007.07.015

H. Hori, A. Yamamoto, K. Koike, S. Kutsuna, I. Osaka, R. Arakawa, “Persulfate-induced photochemical decomposition of a fluorotelomer unsaturated carboxylic acid in water”, Water Res, 2007, 41, 2962-2968. DOI: 10.1016/j.waters.2007.02.033

S. Kutsuna, H. Hori, “Rate constants for aqueous-phase reactions of SO4- with C2F5C(O)O- and C3F7C(O)O- at 298 K, Int. J. Chem. Kinet, 2007, 39, 276-288. DOI: 10.1002/kin.20239

H. Hori, A. Yamamoto, K. Koike, S. Kutsuna, I. Osaka, R. Arakawa, “Photochemical decomposition of environmentally persistent short-chain perfluorocarboxylic acids in water mediated by iron(II)/(III) redox reactions”, Chemosphere, 2007, 68, 572-578. DOI: 10.1016/j.chemosphere.2006.12.038

堀　久男、山本亜理、忽那周三、過硫酸イオンを用いた水中のパーフルオロオクタン酸(PFOA)およびその関連物質の光分解、用水と廃水、2006, 48, 1081-1087.

S. Kutsuna, Y. Nagaoka, K. Takeuchi, H. Hori, “TiO2-induced heterogeneous photodegradation of a fluorotelomer alcohol in air”, Environ. Sci. Technol, 2006, 40, 6824-6829. DOI: 10.1021/es060852k

H. Hori, Y. Nagaoka, A. Yamamoto, T. Sano, N. Yamashita, S. Taniyasu, S. Kutsuna, I. Osaka, R. Arakawa, “Efficient decomposition of environmentally persistent perfluorooctanesulfonate and related fluorochemicals using zerovalent iron in subcritical water”, Environ. Sci. Technol, 2006, 40, 1049-1054. DOI: 10.1021/es0517419

H. Hori, A. Yamamoto, S. Kutsuna, “Efficient photochemical decomposition of long-chain perfluorocarboxylic acids by means of an aqueous/liquid CO2 biphasic system”, Environ. Sci. Technol, 2005, 39, 7692-7697. DOI: 10.1021/es050753r

H. Hori, K. Koike, Y. Sakai, H. Murakami, K. Hayashi, K. Nomiya, “New application of glycerin from a photochemical approach: dihydrogen formation from aqueous glycerin by use of giant polyoxometalate photocatalysts”, Energy & Fuels, 2005, 19, 2209-2213. DOI: 10.1021/ef050157i

H. Hori, A. Yamamoto, E. Hayakawa, S.Taniyasu, N. Yamashita, S. Kutsuna, H. Kitagawa, R. Arakawa, “Efficient decomposition of environmentally persistent perfluorocarboxylic acids using persulfate as a photochemical oxidant” Environ. Sci. Technol, 2005, 39, 2383-2388. DOI: 10.1021/es0484754

H. Hori, E. Hayakawa, H. Einaga, S. Kutsuna, K. Koike, T. Ibusuki, H. Kitagawa, R. Arakawa, “Decomposition of Environmentally persistent perfluorooctanoic acid in water by photochemical approaches”, Environ. Sci. Technol, 2004, 38, 6118-6124. DOI: 10.1021/es049719n

H. Hori, E. Hayakawa, N. Yamashita, S. Taniyasu, F. Nakata, Y. Kobayashi, “High-performance liquid chromatography with conductimetric detection of perfluorocarboxylic acids and perfluorosulfonates”, Chemosphere, 2004, 57, 273-282. DOI: 10.1016/j.chemosphere.2004.05.028

H. Hori, E. Hayakawa, K. Koike, H. Einaga, T. Ibusuki, "Decomposition of nonafluoropentanoic acid by heteropolyacid photocatalyst H3PW12O40 in aqueous solution", J. Mol. Catal. A: Chem. 2004, 211, 35-41. DOI: 10.1016/j.molcata.2003.09.029

H. Hori, Y. Takano, K. Koike, S. Kutsuna, H. Einaga, T. Ibusuki, "Photochemical decomposition of pentafluoropropionic acid to fluoride ions with a water-soluble heteropolyacid photocatalyst", Appl. Catal. B: Environ. 2003, 46, 333-340. DOI: 10.1016/S0926-3373(03)00225-X

B. Gholamkhass, K. Koike, N. Negishi N, H. Hori, T. Sano, K. Takeuchi,” Adjacent- versus remote-site electron injection in TiO2 surfaces modified with binuclear ruthenium complexes”, Inorg. Chem. 2003, 42, 2919-2932. DOI: 10.1021/ic0341237

H. Hori, Y. Takano, K. Koike, K. Takeuchi, H. Einaga, "Decomposition of Environmentally Persistent Trifluoroacetic Acid to Fluoride Ions by a Homogeneous Photocatalyst in Water", Environ. Sci. Technol. 2003, 37, 418-422. DOI: 10.1021/es025783y

H. Hori, Y. Takano, K. Koike, Y. Sasaki, "Efficient Rhenium-Catalyzed Photochemical Carbon Dioxide Reduction Under High Pressure", Inorg. Chem. Commun. 2003, 6, 300-303. DOI: 10.1016/S1387-7003(02)00758-X

K. Koike, N. Okoshi, H. Hori, K. Takeuchi, O. Ishitani, H. Tsubaki, I.P. Clark, M.W. George, F.P.A. Johnson, J.J. Turner, "Mechanism of the Photochemical Ligand Substitution Reactions of fac-[Re(bpy)(CO)3(PR3)]+ Complexes and the Properties of Their Triplet Ligand-Field Excited States", J. Am. Chem. Soc. 2002, 124, 11448-11455. DOI: 10.1021/ja017032m

H. Hori, K. Koike, Y. Suzuki, M. Ishizuka, J. Tanaka, K. Takeuchi, Y. Sasaki, High- pressure photocatalytic reduction of carbon dioxide using [fac-Re(bpy)(CO)3(POiPr)3]+ (bpy=2,2’-bipyridine), J. Mol. Catal. A: Chem. 2002, 179, 1-9.

堀　久男, C. Six, W. Leitner, 超臨界および液体二酸化炭素を反応媒体として用いたポリフェニルアセチレン合成、高分子論文集. 2001, 58, 489-494.

A. Fürstner, L. Ackermann, K. Beck, H. Hori, D. Koch, K. Langemann, M. Liebl, C. Six and W. Leitner, Olefin metathesis in supercritical carbon dioxide, J. Am. Chem. Soc. 2001, 123, 9000-9006.

S. Sasaki, T. Amano, S. Ozawa, T. Masuyama, D. Citterio, H. Hisamoto, H. Hori, K. Suzuki, Synthesis of novel Hg2+ receptors based on N-benzyloxyamide derivatives and their application to anion-selective electrodes, J. Chem. Soc., Perkin Trans. 1. 2001, 1366-1371.

H. Hori, C. Six and W. Leitner, Microstructure and morphology of polyphenylacetylene prepared in compressed carbon dioxide, Appl. Organometal. Chem. 2001, 15, 145-147.

B. Gholamkhass, K. Koike, N. Negishi, H. Hori and K. Takeuchi, Synthesis and characterization of ruthenium(II) molecular assemblies for photosensitization of nanocrystalline TiO2: utilization of hydroxyl grafting mode, Inorg. Chem. 2001, 40, 756-765.

K. Koike, J. Tanabe, S. Toyama, H. Tsubaki, K. Skamoto, J.R. Westwell, F.P.A. Johnson, H. Hori, H. Saito and O. Ishitani, New synthetic route to biscarbonylbipyridinerhenium(I) complexes cis,trans-　[Re(X2bpy)(CO)2(PR3)(Y)]n+ (X2bpy = 4,4’-X2-2,2’-bipyridine) via photochemical ligand substitution reactions, and their photophysical and electrochemical properties, Inorg. Chem. 2000, 39, 2777-2783.

H. Hori, K. Koike, K. Takeuchi, Y. Sasaki, Rhemium-mediated photochemical carbon dioxide reduction in compressed carbon dioxide, Chem. Lett. 2000, 522-523.

H. Hori, K. Koike, K. Takeuchi, O. Ishitani, Photocatalytic reduction of acetylpyridine to pinacol using [fac-Re-(bpy)(CO)3(4-MeCOpy)]+ (bpy=2,2'-bipyridine,py=pyridine), Chem. Lett. 2000, 376-377.

H. Hori, C. Six and W. Leitner, Rhodium-catalyzed phenylacetylene polymerization in compressed carbondioxide, Macromolecules 1999, 32, 3178-3182.

H. Hori, J. Ishihara, K. Koike, K. Takeuchi, T. Ibusuki, O. Ishitani, Photocatalytic reduction of carbon dioxide using [fac-R(bpy)(CO)3(4-Xpy)]+(Xpy = pyridine derivatives), J. Photochem .Photobiol., A: Chem. 1999, 120, 119-124.

H. Hori, J. Ishihara, M. Ishizuka, K. Koike, K. Takeuchi, T. Ibusuki, O. Ishitani, Applications of electrospray mass spectrometry and high performance liquid chromatography in the elucidation of photocatalytic CO2-fixation reactions, Stud. Surf. Sci.Catal. 1998, 114, 557-560.

H. Hori, J. Ishihara, K. Koike, K. Takeuchi, T. Ibusuki, J. Tanabe, O. Ishitani, Electrospray mass spectrometric detection of neutral metal bipyridine complexes using sodium ions and its application in the analysis　of a photochemical ligand substitution reaction, Anal.Sci. 1998, 14, 287-292.

H. Hori, J. Ishihara, K. Koike, K. Takeuchi, T. Ibusuki, O. Ishitani, Photoinduced formation of [fac-Re(bpy)(CO)3CN] from [fac-Re(bpy)(CO)3(4-CNpy)]+ (bpy=2,2'- bipyridine,py=pyridine): CN group rearrangement of a cyanopyridine ligandonto central metal, Chem. Lett. 1997, 1249-1250.

H. Hori, K. Koike, M. Ishizuka, K. Takeuchi, T. Ibusuki, O. Ishitani, Preparation and characterization of[Re(bpy)(CO)３L][SbF６](L=phosphine,phosphate), J. Organomet. Chem. 1997, 530, 169-176.

K. Koike, H. Hori, M. Ishizuka, J.R. Westwell, K. Takeuchi, T. Ibusuki, K. Enjoji, H. Konno, K. Sakamoto, O. Ishitani, Key process of the photocatalytic reduction of CO2 using [Re(4,4’-X2-bipyridine)(CO)3PR3]+ (X = CH3, H, CF3; Pr3 = phosphorus ligands): dark reaction of the one-electron-reduced complex with CO2, Organometallics 1997, 16, 5724-5729.

H. Hori, F.P.A. Johnson, K. Koike, K. Takeuchi, T. Ibusuki, O. Ishitani, Photochemistry of [Re(2,2'-bipyridine)(CO)３PPh３]＋ in the presence of triethanolamine associated with photoreductive fixation of carbon dioxide: participation of a chain mechanism, J. Chem.Soc., Dalton Trans. 1997, 1019-1023.

H. Hori, J. Ishihara, K. Koike, K. Takeuchi, T. Ibusuki, O. Ishitani Electrospray mass spectrometric detection of neutral rhenium bipyridine complexes using NaNO3 as an ionization agent, Chem. Lett. 1997, 273-274.

堀　久男、石谷　治、竹内浩士、指宿堯嗣、レニウム錯体を用いた二酸化炭素の光還元、資源と環境 1997, 6, 25-33.

H. Hori, K. Koike, M. Ishizuka, J. R. Westwell, K. Takeuchi, T. Ibusuki, O. Ishitani, High performance liquid chromatographic characterization of rheniumbipyridine complexes with phosphorus ligands, Chromatographia 1996, 43, 491-495.

H. Hori, O. Ishitani, K. Koike, K. Takeuchi, T. Ibusuki, Electrospray mass spectrometric detection of unstable rhenium complexes as reaction intermediates of photochemical CO２-fixation, Anal. Sci. 1996, 12, 587-590.

H. Hori, F.P.A. Johnson, K. Koike, O. Ishitani, T. Ibusuki, Efficient photocatalytic CO２ reduction using [Re(bpy)(CO)３{P(OEt)３}]＋, J. Photochem. Photobiol. A: Chem. 1996, 96, 171-174.

堀　久男、石谷　治、小池和英、竹内浩士、指宿堯嗣、ホスファイト配位子を有するレニウムビピリジン錯体の二酸化炭素光触媒還元能、資源と環境 1996, 5, 87-91.

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原著論文（査読付き）　/　解説・総説・著書・国際学会プロシーディング　/　特許

解説・総説・著書・国際学会プロシーディング

堀　久男、PFASの規制動向と対応技術、第4章第1節、「有機フッ素材料(フッ素ポリマー等）の分解・再資源化技術」、㈱技術情報協会、2024年6月刊行．

堀　久男、PFAS（有機フッ素化合物）の現状及び規制の影響と今後の対応、第5章第2節、「機能性有機フッ素材料の分解・無機化技術」、㈱情報機構、2024年3月刊行．

堀　久男、PFASとは何か、神奈川大学評論、2023, (104),140-145.
　　　　　
H. Hori, Mineralization of Next-generation Per-and Polyfluorinated Alkyl Substances by Use of Superheated Water, In Perfluoroalkyl Substances, B. Ameduri, ed, Royal Society of Chemistry, 2023, chapter 13. DOI: 10.1039/9781839167591
　　　　　
堀　久男、有機フッ素化合物の分解・再資源化反応の開発、化学工業、2019, 70(8), 15-20.
　　　　　
堀　久男、環境中で検出される有機ケイ素化合物―残留性の解明状況とこれからの課題、化学、2019, 75(1), 70-71.
　　　　　
堀　久男、光化学的手法による水中からのレニウムの効率的な回収、環境管理、2017, 53(12), 20-23.
　　　　　
堀　久男、フッ素化合物の分解と環境化学、共立出版、2017年11月発行.

堀　久男、光化学反応によるレニウムの高効率回収、ペトロテック、2017, 40 (8), 665-669.

堀　久男、有機フッ素化合物の分解反応の開発、ファルマシア、2014, 50 (1), 54-58.

堀　久男、排水・汚水処理技術集成　vol.2、第3章総説、「化学処理技術」、第１節、「フッ素系イオン液体の熱水分解」、㈱エヌ・ティー・エス、2013年12月28日刊行．

堀　久男、有機フッ素化合物をはじめとする環境負荷物質の分解・無害化反応の開発、水環境学会誌、2013,36(9), 331-334.

堀　久男、過塩素酸イオンの環境残留性と対策技術の研究動向、ぶんせき、2013,(8), 458-463.

堀　久男、フッ素樹脂の最新動向、澤田英夫監修、第13章、「機能性フッ素化合物の分解反応の開発」㈱シーエムシー出版、2013年4月1日発行．

堀　久男、世界の化学品規制・ルールの解釈とその違反回避のための実務、第6章7節、「有機フッ素化合物（PFOS／PFOA）」、㈱技術情報協会、2012年12月28日刊行．

堀　久男、機能性フッ素ポリマーおよび関連物質の分解・再資源化反応の開発、高分子、2011,60 (12),856-858.

堀　久男、光酸化剤や熱水を用いた有機フッ素化合物の分解・無害化技術、水と水技術、2009,(3), 88-93.

H. Hori, Y.Nagaoka, M. Murayama, S. Kutsuna, Efficient decomposition of environmentally persistent perfluorocarboxylic acids and related chemicals using persulfate in hot water, Proceedings of 2nd European Conference on Environmental Applications of Advanced Oxidation Processes (CD), 2009, N10, 1-6 .

堀　久男、研究室紹介（独）産業技術総合研究所　環境管理技術研究部門　未規制物質研究グループ　―有機フッ素化合物の環境分析、環境動態解明、分解・無害化反応の開発―、環境浄化技術、2009, 8(2), 59-61.

H. Hori, Y. Nagaoka, A. Yamamoto, T. Sano, S. Kutsuna, I. Osaka, R. Arakawa, Efficient decomposition of perfluoroalkylsulfonates using iron in subcritical water, in Persistent Organic Pollutants (POPs) Research in Asia(Editor: M. Morita), pp. 173-179 (2008).

堀　久男、PFOS・PFOA関連物質の分解・無害化、環境浄化技術、2008,7(8), 31-36.

堀　久男、PFOS・PFOA分解・無害化反応システムの開発、環境技術、2008,37(5), 16-21.

堀　久男、有機フッ素化合物の分解・無害化反応システムの開発、触媒、2008, 50(3), 289-294.

堀　久男、国内外におけるＰＦＯＳ/ＰＦＯＡの最新規制動向と対応策、第1章PFOS/PFOA概論、第2章PFOS/PFOAの規制動向、第3章対策技術の開発状況、㈱技術情報協会、2008年3月31日発行．

堀　久男、ヘテロポリ酸光触媒や過硫酸イオンを用いたＰＦＣＡ類の分解・無害化、 工業材料、2007, 55(12), 66-68.

H. Hori, Y. Nagaoka, A. Yamamoto, T. Sano, S. Kutsuna, I. Osaka, R. Arakawa, Efficient decomposition of perfluoroalkylsulfonates using iron in subcritical water, Organohalogen Compounds, 2007, 69, 169-172.

堀　久男、環境残留性有機フッ素化合物の分解反応システムの開発, 化学バイオつくば財団ニュース,第63号，2-4．

堀　久男、第15回化学・バイオつくば賞受賞の功績「環境に残りやすい有機フッ素化合物を分解・無害化する反応システムの開発」産総研 Today, 2007, 7, 22-22.

堀　久男、各種手法による有機物の分解技術、第2章第1節、有機フッ素化合物の分解技術の開発、㈱情報機構、2007年5月30日発行．

H. Hori, Y. Nagaoka, A. Yamamoto, T. Sano, N. Yamashita, S. Taniyasu,S. Kutsuna, I. Osaka, R. Arakawa, Efficient decomposition of environmentally persistent perfluoroalkylsulfonates using zero-valent iron in subcritical water, Preprints of Extended Abstracts Presented at the 232nd ACS National Meeting, 2006, 46, 844-848.

堀　久男、環境残留性の高い有機フッ素化合物を無害化―PFOSを亜臨界水と鉄粉で効果的に分解―、OHM, 2006, 93 (7), 4-5.
堀　久男、亜臨界水で有機フッ素化合物を無害化、産総研 Today, 2006, 6, 28-29.

堀　久男、機能性材料として使用される有機フッ素化合物の環境残留性と対策技術の研究状況、燃料電池、2005, 4, 83-88.

H. Hori, A. E. Hayakawa, Yamamoto, N. Yamashita, S.Taniyasu, H. Einaga, S. Kustsuna, H. Kitagawa, R. Arakawa, Efficient decomposition of perfluorocarboxylic acids in water by photochemical approaches, Organohalogen Compounds, 2005, 67, 778-778C.

堀　久男、残留性有機フッ素化合物の光触媒分解 、平成１６年度光技術動向調査報告書 [（財）光産業技術振興協会]、2005, 562-563.

堀　久男、光触媒で環境残留性有機フッ素化合物を分解　ヘテロポリ酸光触媒を利用した難分解性環境負荷物質の無害化・再資源化法の開発、AIST Today, 2005, 5, 28.

堀　久男、環境中パーフルオロカルボン酸の起源、化学と工業、2004, 57, 1310.

堀　久男、炭素―フッ素結合を切断できる光触媒を発見　有機フッ素化合物の環境無害化・再資源化への道を拓く、AIST Today, 2003, 9, 11.

堀　久男、 圧縮二酸化炭素を反応媒体および反応原料とした光触媒反応、産業と環境、2001, 2, 26-28.

堀　久男、圧縮二酸化炭素に溶解するレニウム錯体の合成とそれを用いた二酸化炭素の光還元、JASCO Report, 2000, 4, 29-31.

堀　久男、液体および超臨界二酸化炭素を反応媒体＋反応原料とした錯体光触媒反応、Science & Technonews in Tsukuba, 2000, 55, 18-19.

堀　久男、超臨界二酸化炭素を反応媒体とした高分子合成、機能材料、2000, 20, 20-26.

堀　久男、圧縮二酸化炭素を反応媒体とした錯体光触媒反応、NIREニュース、2000, 11, 1-3.

H. Hori, C. Six and W. Leitner, Homogeneous catalysis in compressed carbon dioxide: phenylacetylene polymerization, Proceedings of 6th International Meeting on Supercritical Fluids,　1999, 313-316.

堀　久男、金属錯体による二酸化炭素の光還元、NIREニュース、1997, 6, 1-3.

堀　久男、エレクトロスプレーイオン化質量分析法による金属錯体の光反応中間体の検出、化学と工業、1996, 49, 1574.

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原著論文（査読付き）　/　解説・総説・著書・国際学会プロシーディング　/　特許

特許

堀　久男、フッ素原子含有ポリマーの分解方法、及びフッ素原子含有ポリマーの分解装置、出願人：学校法人神奈川大学、2023、日本国特許　No.7258319.

堀　久男、フッ素原子含有ポリマーの分解方法、及びフッ素原子含有ポリマーの分解装置、出願人：学校法人神奈川大学、2020、日本国特許　No.6711977.

Hisao Hori, "Method for recovering rhenium, method for selectively recovering rhenium from a solution including rhenium and one or more other metals, and method for enriching rhenium in a solution including rhenium and one or more other metals", Kanagawa University, Asaka Riken Co. Ltd.2019, United States Patent No. US10480048 B2.
　
Hisao Hori, "Method for recovering rhenium, method for selectively recovering rhenium from a solution including rhenium and one or more other metals, and method for enriching rhenium in a solution including rhenium and one or more other metals", Kanagawa University, Asaka Riken Co. Ltd.2019, Chinese Patent No. CN107849641 (B).
　
Hisao Hori, "Method for recovering rhenium, method for selectively recovering rhenium from a solution including rhenium and one or more other metals, and method for enriching rhenium in a solution including rhenium and one or more other metals", Kanagawa University, Asaka Riken Co. Ltd.2018, Eurasian Patent No. EP2752431 (B1).
　
堀　久男、加藤昌明、フッ素系有機化合物の分解方法、及びフッ素系化合物の分解装置 、出願人：学校法人神奈川大学、デノラ・ペルメレック(株)、2018、日本国特許　No.6284188.
　
堀　久男、レニウムの回収方法、レニウムとその他の金属とを含む溶液からレニウムを選択的に回収する方法、及びレニウムとその他の金属とを含む溶液にてレニウムの含有比率を高める方法 、出願人：学校法人神奈川大学、2016、日本国特許　No.5987244.
　　　　
堀　久男、レニウムの回収方法、出願人：学校法人神奈川大学、2016、日本国特許　No.5987239.

A. Watakabe, Y. Morizawa, H. Hori, T. Sakamoto, T. Fujita, K. Ishikawa, “Method for producing organic compound having sulfo group, method for producing liquid composition, and method for hydrolyzing organic compound having fluorosulfonyl group”, Asahi Glass Co. Ltd.,2016, Chinese Patent No. CN103764691 (B)

A. Watakabe, Y. Morizawa, H. Hori, T. Sakamoto, T. Fujita, K. Ishikawa, “Method for producing organic compound having sulfo group, method for producing liquid composition, and method for hydrolyzing organic compound having fluorosulfonyl group”, Asahi Glass Co. Ltd.,2016, European Patent No. EP2752431 (B1)


渡壁 淳、森澤義富、堀 久男、坂本峻彦、藤田智行、石川佳奈、スルホ基を有する有機化合物の製造方法、液状組成物の製造方法およびフルオロスルホニル基を有する有機化合物の加水分解処理方法、出願人：旭硝子株式会社、2016、日本国特許　No.5842919.

A. Watakabe, Y. Morizawa, H. Hori, T. Sakamoto, T. Fujita, K. Ishikawa, “Method for producing organic compound having sulfo group, method for producing liquid composition, and method for hydrolyzing organic compound having fluorosulfonyl group”, Asahi Glass Co. Ltd.,2015, United States Patent No. 6875902.

堀　久男、忽那周三、フッ素化カルボン酸類の分解方法、出願人：産業技術総合研究所理事長、2012、日本国特許　No.5071929.

堀　久男、忽那周三、フッ素系イオン交換樹脂膜の分解方法、出願人：産業技術総合研究所理事長、2012、日本国特許　No.4941997.

堀　久男、フッ素系有機化合物の熱水分解法、出願人：産業技術総合研究所理事長、2011、日本国特許　No. 4788946.

堀　久男、忽那周三、フルオロカルボン酸類の分解方法、出願人：産業技術総合研究所理事長、2009、日本国特許　No.4389058.

忽那周三、堀　久男、難分解性フッ素化カルボン酸の分解方法、出願人：産業技術総合研究所理事長、2009、日本国特許　No.4284413.

堀　久男、燃料油に含まれる硫黄化合物の光酸化触媒、出願人：産業技術総合研究所理事長、2008、日本国特許　No.4061375.

堀　久男、永長久寛、フッ素系有機化合物の光分解法、出願人：産業技術総合研究所理事長、2007、日本国特許　No. 3937006.

堀　久男、永長久寛、フッ素系高分子量化合物の光分解法、出願人：産業技術総合研究所理事長、2006、日本国特許　No. 3837468.

堀　久男、佐々木義之、二酸化炭素からのジアルキルホルムアミドの製造方法、出願人：産業技術総合研究所理事長、2006、日本国特許　No. 3757275.

H. Hori, H. Einaga, “Method decomposing fluorine-containing organic material”, National Institute of Advanced Science & Technology, 2005, United States Patent No. 6875902

堀　久男、二酸化炭素の光還元方法、出願人：産業技術総合研究所理事長、2004、 日本国特許　No. 3590837.

堀　久男、ピナコール化合物の製造方法、出願人：工業技術院長、2000、日本国特許 No.3051929.

堀　久男、中性金属錯体の質量分析方法、出願人：工業技術院長、1999、日本国特許 No.2905872.

堀 久男、水銀検出材および水銀の分析方法、出願人：工業技術院長、1996、日本国特許 No.2517880.

H. Hori, Y. Kawakyu, H. Ishikawa, M. Mashita, “Methods of manufacturing III-V group compounds semiconductor”, Toshiba Corporation, 1994, United States Patent No.5300185.